Recent Advances in Cyanamide Chemistry: Synthesis and …
WEBApr 12, 2017 · Cyanamide-based radical cascade reactions are emerging as an important tool to access nitrogen-containing polycyclic frameworks. These compounds are key intermediates in heterocyclic natural products.
Cyanamide - Wikipedia
WEBCyanamide is an organic compound with the formula C N 2 H 2. This white solid is widely used in agriculture and the production of pharmaceuticals and other organic compounds. It is also used as an alcohol-deterrent drug. The molecule features a nitrile group attached to an amino group.
Rational design of carbon nitride photocatalysts by identification …
WEBJul 8, 2016 · We exploit this knowledge for the rational design of a carbon nitride polymer populated with cyanamide groups, yielding a material with 12 and 16 times the hydrogen evolution rate and apparent...
Recent Advances in Cyanamide Chemistry: Synthesis and …
WEBApr 12, 2017 · In this review, we discuss recent advances (since 2012) in the chemistry of cyanamides and detail their application in cycloaddition chemistry, aminocyanation reactions, as well as electrophilic cyanide-transfer agents and their unique radical and coordination chemistry.
Cyanamide - an overview | ScienceDirect Topics
WEBCyanamide causes inhibition of alcohol dehydrogenase resulting in accumulation of acetaldehyde in individuals concomitantly exposed to alcohol. The resulting disulfiram-like reaction is characterized by facial flushing, headache, nausea, vomiting, sweating, chest pain, hypotension, weakness, blurred vision, confusion, and difficulty in breathing.
Calcium cyanamide - Wikipedia
WEBCalcium cyanamide, also known as Calcium carbondiamide, Calcium cyan-2°-amide or Calcium cyanonitride is the inorganic compound with the formula CaCN 2. It is the calcium salt of the cyanamide (CN2−. 2) anion. This chemical is used as fertilizer [3] and is commercially known as nitrolime.
Iron-mediated desulphurization approach: synthesis of …
WEBJan 6, 2022 · Iron-mediated efficient multi-component method has been demonstrated for the synthesis of substituted cyanamides from isothiocyanates under mild reaction conditions. Subsequent nucleophilic addition and desulfurization are involved in this proposed synthetic methodology.
Selective ensembles in supported palladium sulfide ... - Nature
WEBJul 6, 2018 · Thus, the synthesis of trimeric ensembles 36, 37, 38, 39, and the presence of electronic modifiers reducing the hydrogen uptake of Pd and the formation of subsurface hydrides, are key parameters...
The Structures of Cyanamide and Carbodiimide
WEBReactions of Titanocene Bis (trimethylsilyl)acetylene Complexes with Carbodiimides: An Experimental and Theoretical Study of Complexation versus C–N Bond Activation. Journal of the American Chemical Society 2012, 134 (38) , 15979-15991. https://doi.org/10.1021/ja3070649.
Cyanamide - an overview | ScienceDirect Topics
WEB10.07.5.2 Cyanamide. Cyanamide (carbodiimide), like disulfiram, is used therapeutically (Temposil) as an inhibitor of ALDH to discourage individuals from consuming alcohol. It is currently used for this purpose in Europe, Canada, and Japan but not in the United States.
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